Graphite, Explosives & Accessories
Graphite Market Overview
The global graphite market is valued at $24599.9 million in 2023, and it is projected to witness a CAGR of 7.4% during the forecast period (2020–2030). This is primarily attributed to the growing demand for graphite products in the metallurgy and electronics industries across the globe. Furthermore, graphite is widely consumed during the production of lithium-ion (Li-ion) batteries, which is likely to pave the way for the adoption of graphite in the automotive industry, which, in turn, will boost the global graphite industry.
Owing to the lockdown in various countries, the operations of various industries, including metallurgy and automotive, were temporarily halted or reduced, in order to curtail the spread of the disease. Since graphite is widely used in the production of various crucial components of automobiles and industrial machinery, the market for this material has been negatively affected by the pandemic.
The graphite market accounted for 2,892 kilo metric ton in 2020, and it is expected to register a CAGR of 5% during the forecast period, 2021-2026. The COVID-19 outbreak presented a challenging industry arena for the graphite market, as it slowed down the demand from the key end-user industries, like electronics, metallurgy, and automotive (including electric vehicles), owing to the lockdown measures of the COVID-19 pandemic. Furthermore, the production facilities of electronics parts were halted, owing to the logistics slowdown and unavailability of the workforce across the world.
Over the short term, the major factors driving the growth of the market studied include the augmenting demand from the burgeoning lithium-ion (Li-ion) battery industry and the rise in steel production in Asia and the Middle East. On the flip side, the development of substitute anode materials for lithium-ion batteries in high-end applications, stringent environmental regulations, and the impact of the COVID-19 outbreak are expected to hinder the growth of the market studied.
The growing usage of graphite in green technologies and the popularity of graphene are projected to offer opportunities for the manufacturers over the forecast period. The Asia-Pacific region is expected to dominate the market, and it is also likely to witness the highest CAGR during the forecast period.
The New Strategic Mineral
Graphite is one of only two naturally occurring forms of pure carbon, the other being diamonds. Graphite occurs in a two dimensional, planar molecular structure whereas diamonds have a three dimensional crystal structure. Graphite generally occurs as flakes, which are multiple layers of graphene held together by weak bonds. Graphene is a single, one atom thick layer of carbon atoms arranged in a “honeycomb” or “chicken wire” pattern. It has been estimated that there are three million layers of graphene in a one millimeter thickness of graphite. The delamination or exfoliation of graphite flakes is therefore one method of making graphene.
Graphite is formed naturally through the metamorphism of carbon rich materials in rock which leads to the formation of either crystalline flake graphite, fine grained amorphous graphite, or crystalline vein or lump graphite. Graphite is a non-metal but has many properties of metals. It is an excellent conductor of heat and electricity and has the highest natural strength and stiffness of any material. It maintains its strength and stability to temperatures in excess of 3,600°C and is very resistant to chemical attack. At the same time it is one of the lightest of all reinforcing agents and has high natural lubricity.
Future prospect of Graphite Industry
Excellence In Energy Efficiency
The graphite market is expected to grow at a significant rate during the forecast period, majorly driven by the augmenting demand from burgeoning lithium-ion battery industry. Graphite is flexible in nature and has both non-metallic and metallic properties, which makes it appropriate for a diverse range of industrial applications. The metallic properties include electrical and thermal conductivity, while the non-metallic properties of graphite include high thermal resistance, chemical inertness, and lubricity.
Augmenting Demand From Lithium-Ion Battery Industry
Uncoated spherical graphite, coated spherical graphite (CSPG) and lithium-ion anode paste are imperative as anode material in lithium ion batteries for mobile consumer appliances, electric vehicles and stationary energy storages. The three main demand drivers for CSPG include transportation batteries (significant growth), stationary or commercial or utility grid-storage batteries (exponential growth), and consumer electronics batteries (moderate growth).
The current consumption for Li-ion batteries is 105,000 tons (60,000 natural CSPG and 45,000 synthetic). As there is no CSPG production in North America, two United States based graphite companies, Graphite One and Alabama Graphite have included facilities for turning graphite concentrate into coated, purified, spherical graphite (also known as CPSG) in order to capture the fast growing lithium ion battery market. Hence, with such boom in the lithium-ion battery industry, the demand for graphite is projected to increase substantially during the forecast period.
Electronics Industry To Dominate The Market
The applications of graphite products in the electronics industry include the manufacturing of silicon semiconductor, LED chips, lithium-ion batteries and LCD panels. They are used in electronics industry as the processes involved to manufacturer components involve high temperature and corrosive environment while these graphites are impressively heat and corrosion resistant. Graphite is mostly used in the semiconductor and LED industry for polysilicon production. The products made from graphite include cleaned electrodes for polysilicon separation, heat shields, thermal insulation components and gas ducts for converters.
The Future Of Battery Supply Chains
Battery and EV manufactures are scrutinized by the public even more than other industries. The sector fuels the shift towards a greener mobility and therefore needs to achieve this with minimal adverse effects on the environment. Attaining a clean mobility at the cost of causing avoidable environmental impacts is at least very questionable. Therefore, the current discussions circulating around supply chain transparency will continue to be more important. Downstream actors need to be aware of issues in the upstream. This paper pointed out some of the issues related to lithium mining and the production of graphite. The impacts of production of battery raw materials need to be studied further in order take the right decisions when trying to mitigate environmental and socioeconomic impacts. A large number of companies, enterprises and initiatives have committed to responsible sourcing of minerals. As cell manufacturing is very likely to become more important in Europe, it will be key to face issues along the whole battery supply chain.
Asia-Pacific To Dominate The Market Growth
The global graphite market size is projected to grow from $14.83 billion in 2021 to $25.70 billion in 2028 at a CAGR of 8.2% in the forecast period, 2021-2028.
Asia-Pacific is the largest market for graphite, accounting for over 40% of the global market in 2021. The growth of the graphite market in Asia-Pacific is primarily due to the growth of its end-user industries, such as electronics, foundry, and photovoltaic in countries, like China, India, Japan, and South Korea.
The product is a kind of elemental carbon that is one of the few elements found in its natural state. It combines metallic and non-metallic qualities, making it ideal for a whole variety of industrial applications. It has high electrical and thermal conductivity, exceptional thermal stability and lubricity.
In the coming decades, the industry is expected to face major market shifts, as the booming Lithium Ion battery industry expected to boost production. The anode in Li ion batteries (LiBs”) is made out of graphite. A graphite anode is one of the things that make it a LiB and there are no substitutes. LiBs are smaller, lighter and more powerful than traditional batteries and have a flat voltage profile meaning they provide almost full power until discharged. They also have no memory effect and a very low rate of discharge when not in use. Almost all portable consumer devices such as laptops, cell phones, MP3 players and cameras use Li ion batteries and they are now rapidly moving into power tools and bigger devices. This has lead to 20% annual growth in the LiB market.
This growth rate is expected to continue as hybrid electric vehicles (“HEV”), plug in electric vehicles (“PEV”) and all electric vehicles (“EV”), and grid storage applications, are huge markets that are all in their infancy. This has significant implications for the LiB and graphite markets. The batteries are large and the potential demand for graphite very significant. By weight, graphite is the largest component in LiBs and they contain 10-15 times more graphite than lithium. Because of losses in the manufacturing process, it actually takes over 30 times as much graphite to make the batteries.
There is up to 10 kgs of graphite in the average HEV and up to 70 kgs in an EV. There is far more in a Tesla Model S. Every million EVs, which is about 1% of the new car market, require in the order of 75,000 tonnes of natural graphite to make the batteries which represents a potential ten per cent increase in flake graphite demand. Because of the small size of the flake graphite market, even modest, conservative EV adoption rates will have a big effect on demand. LiB manufacturing capacity currently under construction would require flake graphite production to more than double by 2025.
The anode material used in LiBs, called spherical graphite (“SPG”), is manufactured from either flake graphite concentrates produced by graphite mines or from synthetic graphite. Only flake graphite which can be economically rounded and upgraded to 99.95% purity can be used. The manufacturing process includes micronization, rounding, purification and heat treatment. The process is expensive and wastes up to 70% of the flake graphite feed. As a result, uncoated spherical graphite currently sells for up to USD3,000/tonne or over three times the price of large flake graphite. Coated spherical graphite sells for USD$4,000 to $12,000 per tonne depending on quality and end market.
Almost all Li ion battery manufacturing currently takes place in China because of the ready availability of graphite, weak environmental standards and low costs. Secure, cost competitive and environmentally sustainable source of graphite are needed in the west
India is a major global producer of flake graphite
The country has been ranked amongst the top five graphite producers by the USGS, with reserves of nearly 11m tonnes.
Graphite occurrences are reported from different states including Jammu and Kashmir, Arunachal Pradesh, Gujarat, Jharkhand, Maharashtra, Karnataka, Kerala, Tamil Nadu, Odisha, Chattisgarh and Rajasthan.
However, the deposits of economic importance are located in Andhra Pradesh, Chattisgarh and Arunachal Pradesh, which are yet to be exploited. As far as mining and processing of graphite is concerned, Jharkhand, Odisha and Tamil Nadu are the only states where operations are being conducted.
Graphite in India
Graphite Reserves Distribution
- Arunachal Pradesh: Holds the largest share of graphite reserves in India, with about 43% of the total graphite found in the country.
- Jammu and Kashmir: Follows with a significant portion of graphite reserves, accounting for about 37% of the country’s total.
- Other states with notable graphite reserves include Jharkhand (6%), Tamil Nadu (5%), and Odisha (3%).
Graphite Production Concentration
- Tamil Nadu (37%), Jharkhand (30%), and Odisha (29%) are the states where most of the graphite production is concentrated.
Active Mining Centers
- Jharkhand: Notable districts for graphite mining include Latehar & Palamu.
- Odisha: Graphite mining is active in Bargarh, Nuapada, Rayagada & Balangir districts.
- Tamil Nadu: The districts of Madurai & Sivagangai are known for graphite mining.
India’s Trade in 2022-23
- During the year 2022-23, India’s export of Graphite, Explosives and Accessories is valued at USD 671.18 US$ which is 39% higher than the previous year. In April-October 2023 export of this sector stood at USD 406.96 Million.
- The top 5 export destinations for India are USA, Egypt, Turkey, Saudi Arab & Mexico.
Challenges For Indian Graphite Industry
Graphite is a form of pure carbon that normally occurs as black crystal flakes and masses. Its unique physical and chemical properties make it well-suited to many industrial applications, including electronics, lubricants, metallurgy, and steelmaking. Global demand for natural graphite doubled between 2006 and 2012. Although Chinese industrial activity has slowed and led to prices falling from the high levels seen in 2011, consumption of smart electronic devices has caused a growth in demand and this may continue to grow as sales of electric and hybrid vehicles require larger batteries. China and India are the largest graphite producers, with over 80% of global production. Chinese graphite, however, is declining in quality while production costs are increasing. China has a 20% export duty on graphite, a 17% value added tax, and has instituted an export licensing system to ensure supply to its domestic economy, creating supply concerns for the rest of the world.
Graphite generally forms from high-grade metamorphism of organic matter in sediments. The three main types of commercially significant natural graphite are crystalline or disseminated flake, crystalline vein or lump, and microcrystalline or amorphous graphite. The largest flake graphite deposits are often relatively low grade. In contrast, vein graphite deposits are smaller and higher grade. Amorphous deposits can range in size but generally produce lower quality graphite with restricted uses. Recent exploration has focused on flake graphite in East Africa, Canada and Australia. The largest deposits are in Mozambique and Tanzania, an area noted for large, high purity flake graphite. This increased exploration activity has resulted in global inferred resources exceeding 800 Mt (USGS, 2015).
The value of graphite deposits depends on grade, purity, size and range of flakes or needles, and the presence of impurities that may have a negative effect on extraction. Pricing is complex and depends on total graphitic carbon (TGC) content; deposits with grades of over 80% TGC are economically viable.
The two main assay methods for measuring TGC are: LECO analysis and Double Loss of Ignition (DLOI). DLOI is normally used as a graphitic indicator, while the LECO method provides a more detailed assessment. DLOI may not always accurately represent the actual TGC values in the rock as the measurements can be affected by the presence of sulphides and calcite (carbonate). Processing flake graphite aims to optimise the liberation of flakes by size (Large: +180μm; Jumbo: +300μm; and Super Jumbo: +500μm flakes) and to maximize grade and recovery. Evaluating the economic potential of graphite samples requires an understanding of the extraction process. Over 80% of graphite demand is still driven by industrial applications. Predictions see the battery sector increasing market share over the next few years with a rebound in the steel industry having potential to also fuel demand.
In the 1990s China dumped graphite on the market to earn foreign exchange which caused a significant decline in prices. Much like rare earths, this essentially killed the industry in the west and graphite prices remained low until about 2005 due to excess production capacity in China. Then the growth in China, the commodity super cycle and resultant demand from the steel industry caused graphite prices to increase until they reached record levels in 2012. Shortages were reported. Unfortunately for the graphite producers, high prices did not last long as a slowdown in the Chinese economy and declining steel demand quickly caused prices to fall back. No new mines were built in the west during this period.
Since that time prices have been sideways to down as the industry waits for steel demand to recover and for the lithium ion battery (“LiB”) market to get big enough to drive prices on its own as has happened with lithium and cobalt. LiBs were not a factor with respect to demand in 2012 but have been growing at 20%pa due to the proliferation of handheld devices such as cell phones, camera, laptops, power tools, etc. Electric vehicles and grid storage are huge markets which are still in their infancy. LiBs already account for 25% of flake graphite demand and manufacturing plants under construction are expected to triple demand by 2021. This will require flake graphite production to double in that period of time
Currently, China produces 70 to 80% of the world’s graphite and 100 per cent of the natural graphite used in LiBs. Because of this dependence on China, as well as the importance of graphite to the economy, both the EU and the US have declared graphite a supply critical mineral.
The future direction of Chinese production will be a significant factor in determining where graphite prices go. Traditionally, Shandong Province was the center of graphite mining in China but its production is declining due to the depletion of ore reserves and stricter enforcement of environmental regulations. As Shandong was the main source of large and extra large flake graphite, production of these grades is also declining. Mining has transitioned to Heilongjiang Province and it is now the major producer. There are two main producing areas in Heilongjiang, Jixi/Mashan and Luobei, both of which produce mainly small flake.
The Jixi/Mashan region is the largest and is operating near full capacity. There do not appear to be any new mines planned or under construction. Luobei was principally built to serve the LiB market and is only operating at 30 per cent capacity. For this reason, it is unlikely small flake prices will increase in the short term until the significant growth in EVs/LiBs consumes this excess capacity.
The market for large and XL flake graphite is much more robust, in part because of declining Shandong production but also because expandable graphite is the fastest growing market along with LiBs. Expandable graphite is principally made from large/XL flake. It is used in thermal management for consumer electronics and many industrial applications including heat and corrosion resistant gaskets and fire retardants. The latter market is expected to grow rapidly as the use of brominated flame retardants is is phased out or banned. Fuel cells and flow batteries are also new and potentially large markets for expandable graphite. Also, the steel industry is a significant user of large flake and its recovery will put additional pressure on large flake prices.
Annual Chinese demand for expandable graphite is approximately 70,000 tonnes. China only produces 25,000tpa of +50 mesh flake and the balance is made up of less desirable +80 mesh flake. The demand for expandable graphite with very high expansion rates is growing even more rapidly and this requires +32 mesh flake graphite. There is currently a shortage of both +50 mesh and +32 mesh material in China as there is in the rest of Asia as well as Europe. China has now started to import +50 mesh concentrates from Madagascar.
In the short to medium term the graphite opportunity is clearly in the large/XL flake markets which are high price and high margin with supply shortages. Longer term, new western sources of small flake production will be required to meet the expected growth in the EV/LiB markets and provide security of supply.